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Technical Paper

Sulphur Poisoning and Regeneration of NOx Trap Catalyst for Direct Injected Gasoline Engines

1999-10-25
1999-01-3504
Sulphur poisoning and regeneration of NOx trap catalysts have been studied in synthetic exhausts and in an engine bench. Sulphur gradually poisoned the NOx storage sites in the axial direction of the NOx trap. During sulphur regenerations, hydrogen was found to be more efficient than carbon monoxide in removing the sulphur from the trap. The sulphur regeneration became more efficient the richer the environment (λ<1) and the higher the temperature (at least 600°C). H2S was found to be the main product during the sulphur regeneration. However, it was possible to reduce the H2S formation and instead produce more SO2 by running with lambda close to one or by pulsing lambda. Even if a relatively large amount of sulphur was removed from the NOx trap, these methods gave a much less efficient regeneration per sulphur atom removed than when running relatively rich constantly. Finally, a model that could explain this observation was proposed.
Technical Paper

A Catalytic NOX After-Treatment System for Heavy-Duty Trucks Using Diesel Fuel as Reducing Agent

1999-10-25
1999-01-3563
An advanced catalytic exhaust after-treatment system addresses the problem of NOX emissions from heavy-duty diesel trucks, relying on real-time catalyst modelling. The system consists of de-NOX catalysts, a device for injection of a reducing agent (diesel fuel) upstream the catalysts, and computer programmes to control the injection of the reducing agent and to model the engine and catalysts in real time. Experiments with 5 different air-assisted injectors were performed to determine the effect of injector design on the distribution of the injected diesel in the exhaust gas stream. A two-injector set-up was investigated to determine whether system efficiency could be increased without increasing the amount of catalyst or the amount of reducing agent necessary for the desired outcome. The results were verified by performing European standard transient cycle tests as well as stationary tests.
Technical Paper

Supervisory Controller for a Light Duty Diesel Engine with an LNT-SCR After-Treatment System

2018-09-10
2018-01-1767
Look ahead information can be used to improve the powertrain’s fuel consumption while efficiently controlling exhaust emissions. A passenger car propelled by a Euro 6d capable diesel engine is studied. In the conventional approach, the diesel powertrain subsystem control is rule based. It uses no information of future load requests but is operated with the objective of low engine out exhaust emission species until the Exhaust After-Treatment System (EATS) light off has occurred, even if fuel economy is compromised greatly. Upon EATS light off, the engine is operated more fuel efficiently since the EATS system is able to treat emissions effectively. This paper presents a supervisory control structure with the intended purpose to operate the complete powertrain using a minimum of fuel while improving the robustness of exhaust emissions.
Technical Paper

OH Radical and Soot Concentration Structures in Diesel Sprays under Low Sooting and Non-Sooting Conditions

2018-09-10
2018-01-1690
In an optically accessible high-pressure/high-temperature (HP/HT) chamber, OH radicals, soot concentration, and OH* chemiluminescence images were captured simultaneously at a constant ambient temperature of 823 K and a gas density of 20 kg/m3, with injection pressures of 800-2000 bar using an injector with nozzle orifice having a diameter of 0.1 mm. Swedish market sold MK1 diesel fuel was used in this study. The optical diagnostic methods used were the two-dimensional laser extinction for the soot concentration measurement, planar laser induced fluorescence for the OH radical measurement, OH* chemiluminescence imaging, and the natural flame luminosity imaging. The objective of this study is to explore the diesel spray structures under the low sooting and non-sooting conditions. In this study, it was found that the OH radical zone in the jet’s upstream region expanded to the jet center and the soot concentration decreased when the fuel injection pressure increased.
Technical Paper

Comparison of Long-Chain Alcohol Blends, HVO and Diesel on Spray Characteristics, Ignition and Soot Formation

2019-01-15
2019-01-0018
Spray characteristics of fossil Diesel fuel, hydrotreated vegetable oil (HVO) and two oxygenated fuel blends were studied to elucidate the combustion process. The fuels were studied in an optically accessible high-pressure/high-temperature chamber under non-combusting (623 K, 4.69 MPa) and combusting (823 K, 6.04 MPa) conditions. The fuel blends contained the long-chain alcohol 2-ethylhexanol (EH), HVO and either 20 vol.% Diesel or 7 vol.% rapeseed methyl ester (RME) and were designed to have a Diesel-like cetane number (CN). Injection pressures were set to 120 MPa and 180 MPa and the gas density was held constant at 26 kg/m3. Under non-combusting conditions, shadow imaging revealed the penetration length of the liquid and vapor phase of the spray. Under combusting conditions, the lift-off length and soot volume fraction were measured by simultaneously recording time-resolved two-dimensional laser extinction, flame luminosity and OH* chemiluminescence images.
Technical Paper

Optical Diagnostics of Spray Characteristics and Soot Volume Fractions of n-Butanol, n-Octanol, Diesel, and Hydrotreated Vegetable Oil Blends in a Constant Volume Combustion Chamber

2019-01-15
2019-01-0019
The effects of using n-butanol, n-octanol, fossil Diesel, hydrotreated vegetable oil (HVO), and blends of these fuels on spray penetration, flame and soot characteristics were investigated in a high-pressure high-temperature constant volume combustion chamber designed to mimic a heavy duty Diesel engine. Backlight illumination was used to capture liquid and vapor phase spray images with a high-speed camera. The flame lift-off length (LOL) and ignition delay were determined by analyzing OH* chemiluminescence images. Laser extinction diagnostics were used to measure the spatially and temporally resolved soot volume fraction. The spray experiments were performed by injecting fuels under non-combusting (623 K) and combusting (823 K) conditions at a fixed ambient air density of 26 kg/m3. A Scania 0.19 mm single straight hole injector and Scania XPI common rail fuel supply system were used to produce injection pressures of 120 MPa and 180 MPa.
Technical Paper

Multi-Objective Optimization of Fuel Consumption and NOx Emissions with Reliability Analysis Using a Stochastic Reactor Model

2019-04-02
2019-01-1173
The introduction of a physics-based zero-dimensional stochastic reactor model combined with tabulated chemistry enables the simulation-supported development of future compression-ignited engines. The stochastic reactor model mimics mixture and temperature inhomogeneities induced by turbulence, direct injection and heat transfer. Thus, it is possible to improve the prediction of NOx emissions compared to common mean-value models. To reduce the number of designs to be evaluated during the simulation-based multi-objective optimization, genetic algorithms are proven to be an effective tool. Based on an initial set of designs, the algorithm aims to evolve the designs to find the best parameters for the given constraints and objectives. The extension by response surface models improves the prediction of the best possible Pareto Front, while the time of optimization is kept low.
Technical Paper

Particulate Emissions in a GDI with an Upstream Fuel Source

2019-04-02
2019-01-1180
Public health risk and resulting stringent emission regulations for internal combustion engines pose a need for solutions to reduce particle emissions (PN). Current PN control approaches include increasing fuel injection pressure, optimizing spray targeting, multiple injection strategies, and the use of tumble flaps together with gasoline particulate filters (GPF). Experiments were performed using a single-cylinder spark-ignited GDI engine equipped with a custom inlet manifold and a port fuel injector located 500 mm upstream. Particulate emissions were measured during stationary medium/high load operation to evaluate the effect of varying the mass split between the direct and upstream injectors. Mixing quality is improved substantially by upstream injection and can thus be controlled by altering the mass split between the injectors.
Technical Paper

Effect of Injection Strategy and EGR on Particle Emissions from a CI Engine Fueled with an Oxygenated Fuel Blend and HVO

2021-04-06
2021-01-0560
Alcohol-based fuels are a viable alternative to fossil fuels for powering vehicles. As a drop-in fuel, an oxygenated fuel blend containing the C8 alcohol 2-ethylhexanol (isomer of octanol), hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) can reduce soot and NOx emissions whilst maintaining engine performance. However, fuel injection strategy significantly affects combustion and hence has been investigated with a view to reducing emissions whilst maintaining engine efficiency. In a single cylinder light-duty compression ignition research engine, the effect of different injection strategies (main, main/post, double pre/main, double pre/main/post injection) and EGR levels (0%, 19%) on specifically NOx, soot emissions and particle size distribution was investigated for three different fuels: fossil diesel fuel, HVO and the oxygenated blend. The blend was designed to have diesel-like combustion properties (cetane number of 52) and had an oxygen content of 5.4% by mass.
Technical Paper

CI Methanol and Ethanol combustion using ignition improver

2019-12-19
2019-01-2232
To act on global warming, CO2 emissions must be reduced. This will require a reduction in the use of fossil fuels for transportation. Because of the large quantities of fossil fuels used in transportation, sources of renewable fuels other than biomass will have to be explored, such as electrofuels synthesized from CO2 using renewable electricity. Potential electrofuels include methanol and ethanol, which have shown promising results in SI engines. However, their low cetane numbers make these fuels unsuitable for CI engines because of their poor auto-ignition qualities. The main objective of this study was to evaluate the viability of using methanol and ethanol in CI engines at compression ratios of 16.7 and 20 with a pilot-main injection strategy in the PPC/CI regime. Single cylinder engine tests on a heavy duty engine were performed under medium load conditions (1262 rpm and 172 Nm).
Technical Paper

Drive Cycle Particulate and Gaseous Emissions from a Parallel Hybrid Combustion Engine and Electric Powertrain

2015-09-06
2015-24-2538
The emissions from a parallel hybrid combustion engine and electric powertrain operated on a modified New European Drive Cycle (NEDC) was investigated in order to determine the relation between emissions and the road and engine load profile. The effect of simulated electric motor assistance during accelerations on emissions was investigated as a means to reduce particulate and gaseous emissions. The time resolved particulate number and size distribution was measured in addition to gaseous emissions. The combustion engine was a downsized, three cylinder spark ignited direct injection (SIDI) turbocharged engine fuelled with gasoline. Electric motor assistance during accelerations was simulated by reduction of the vehicle mass. This reduced engine load during accelerations. Fuel rich engine transients occurred during accelerations. NOx emissions were reduced with electric assistance due to a reduction in engine load.
Technical Paper

Soot Source Term Tabulation Strategy for Diesel Engine Simulations with SRM

2015-09-06
2015-24-2400
In this work a soot source term tabulation strategy for soot predictions under Diesel engine conditions within the zero-dimensional Direct Injection Stochastic Reactor Model (DI-SRM) framework is presented. The DI-SRM accounts for detailed chemistry, in-homogeneities in the combustion chamber and turbulence-chemistry interactions. The existing implementation [1] was extended with a framework facilitating the use of tabulated soot source terms. The implementation allows now for using soot source terms provided by an online chemistry calculation, and for the use of a pre-calculated flamelet soot source term library. Diesel engine calculations were performed using the same detailed kinetic soot model in both configurations. The chemical mechanism for n-heptane used in this work is taken from Zeuch et al. [2] and consists of 121 species and 973 reactions including PAH and thermal NO chemistry. The engine case presented in [1] is used also for this work.
Technical Paper

Soot Sources in Warm-Up Conditions in a GDI Engine

2021-04-06
2021-01-0622
Gasoline direct injection (GDI) engines usually emit higher levels of particulates in warm-up conditions of a driving cycle. Thus, sources of soot formation in these conditions were investigated by measuring particulate numbers (PN) emitted from a single-cylinder GDI engine and their sizes. The combustion was also visualized using an endoscope connected to a high-speed camera. Engine coolant and oil temperatures were varied between 15 and 90oC to mimic warm-up conditions. In addition, effects of delaying the start of ignition (SOI) on the emissions in these conditions were examined. Coolant and oil temperatures were varied individually to identify which factor has most effect on PN emissions. While coolant temperature strongly influenced PN with cold oil, the oil temperature insignificantly affected PN at low coolant temperature. These findings indicate that PN emissions are heavily dependent on the engine block’s temperature, which is dominated by the coolant.
Journal Article

Apparent Soot Size and Concentration in Combusting Diesel Jets at High Gas Pressures and Temperatures Measured by Combining Quasi-Simultaneous LII, Elastic Light Scattering and Light Extinction

2020-04-14
2020-01-0787
A method for measuring apparent soot particle size and concentration in turbulent combusting diesel jets with elevated and inhomogeneous optical density is presented and discussed. The method is based on the combination of quasi-simultaneous Laser Induced Incandescence (LII), Elastic Scattering (ELS) and Light Extinction (LE) measurements exhibiting a high potential for spatially resolved measurements of carbonaceous particles in flames and residual gases at a given instant. The method evaluates the LII signal by calculating the laser fluence across the flame and compensating for signal trapping, allowing measurements where laser extinction between the flame borders reaches values up to 90%. The method was implemented by measuring particle size and concentration in the middle sagittal axis of optically dense, combusting diesel jets at a certain time after the start of combustion.
Journal Article

Water Injection Benefits in a 3-Cylinder Downsized SI-Engine

2019-01-15
2019-01-0034
With progressing electrification of automotive powertrains and demands to meet increasingly stringent emission regulations, a combination of an electric motor and downsized turbocharged spark-ignited engine has been recognized as a viable solution. The SI engine must be optimized, and preferentially downsized, to reduce tailpipe CO2 and other emissions. However, drives to increase BMEP (Brake Mean Effective Pressure) and compression ratio/thermal efficiency increase propensities of knocking (auto-ignition of residual unburnt charge before the propagating flame reaches it) in downsized engines. Currently, knock is mitigated by retarding the ignition timing, but this has several limitations. Another option identified in the last decade (following trials of similar technology in aircraft combustion engines) is water injection, which suppresses knocking largely by reducing local in-cylinder mixture temperatures due to its latent heat of vaporization.
Technical Paper

Dual Fuel Methanol and Diesel Direct Injection HD Single Cylinder Engine Tests

2018-04-03
2018-01-0259
Laws concerning emissions from heavy duty (HD) internal combustion engines are becoming increasingly stringent. New engine technologies are needed to satisfy these new requirements and to reduce fossil fuel dependency. One way to achieve both objectives can be to partially replace fossil fuels with alternatives that are sustainable with respect to emissions of greenhouse gases, particulates and nitrogen oxides (NOx). A suitable candidate is methanol. The aim of the study presented here was to investigate the possible advantages of combusting methanol in a heavy duty Diesel engine. Those are, among others, lower particulate emissions and thereby bypassing the NOx-soot trade-off. Because of methanol’s poor auto-ignition properties, Diesel was used as an igniting sources and both fuels were separately direct injected. Therefore, two separate standard common rail Diesel injection systems were used together with a newly designed cylinder head and adapted injection nozzles.
Technical Paper

Comparative Assessment of Zero CO2 Powertrain for Light Commercial Vehicles

2023-08-28
2023-24-0150
The transport sector is experiencing a shift to zero-carbon powertrains driven by aggressive international policies aiming to fight climate change. Battery electric vehicles (BEVs) will play the main role in passenger car applications, while diversified solutions are under investigation for the heavy-duty sector. Within this framework, Light Commercial Vehicles (LCVs) impact is not negligible and accountable for about 2.5% of greenhouse gas (GHG) emissions in Europe. In this regard, few LCV comparative assessments on green powertrains are available in the scientific literature and justified by the fact that several factors and limitations should be considered and addressed to define optimal powertrain solutions for specific use cases. The proposed research study deals with a comparative numerical assessment of different zero-carbon powertrain solutions for LCV. BEVs are compared to hydrogen-based fuel cells (FC) and internal combustion engines (ICE) powered vehicles.
Technical Paper

Self-Ignition and Early Combustion Process of n-Heptane Sprays Under Diluted Air Conditions: Numerical Studies Based on Detailed Chemistry

2000-10-16
2000-01-2931
This paper reports the numerical studies of self-ignition and early combustion process of n-heptane sprays under various diluted air conditions. The numerical simulations employ a detailed chemistry approach, coupled directly with the computational fluid dynamics (CFD). A “subgrid” Partially Stirred Reactor (PaSR) model has been developed to account for the turbulence-chemistry-interaction. This model has been implemented into the KIVA3V CFD code. A detailed chemical mechanism of reduced size (65 species and 273 elementary reactions) for the n-heptane fuel has been derived and applied to the simulations of spray combustion. The studies focus on sprays injected into a high-pressure constant-volume chamber. Firstly, the validation of the current numerical model has been carried out for the case in which the injection and initial conditions are similar to those used in the “classical” Aachen experiments (50bar and 800K).
Technical Paper

48V Mild-Hybrid Architecture Types, Fuels and Power Levels Needed to Achieve 75g CO2/km

2019-04-02
2019-01-0366
48V mild hybrid powertrains are promising technologies for cost-effective compliance with future CO2 emissions standards. Current 48V powertrains with integrated belt starter generators (P0) with downsized engines achieve CO2 emissions of 95 g/km in the NEDC. However, to reach 75 g/km, it may be necessary to combine new 48V powertrain architectures with alternative fuels. Therefore, this paper compares CO2 emissions from different 48V powertrain architectures (P0, P1, P2, P3) with different electric power levels under various driving cycles (NEDC, WLTC, and RTS95). A numerical model of a compact class passenger car with a 48V powertrain was created and experimental fuel consumption maps for engines running on different fuels (gasoline, Diesel, E85, CNG) were used to simulate its CO2 emissions. The simulation results were analysed to determine why specific powertrain combinations were more efficient under certain driving conditions.
Technical Paper

Characterization of Gaseous and Particle Emissions of a Direct Injection Hydrogen Engine at Various Operating Conditions

2023-09-29
2023-32-0042
This paper investigates the gaseous and particulate emissions of a hydrogen powered direct injection spark ignition engine. Experiments were performed over different engine speeds and loads and with varying air- fuel ratio, start of injection and intake manifold pressure. An IAG FTIR system was used to detect and measure a variety of gaseous emissions, which include standard emissions such as NOX and unburned hydrocarbons as well as some non-standard emissions such as formaldehyde, formic acid, and ammonia. The particle number concentration and size distribution were measured using a DMS 500 fast particle analyzer from Cambustion. Particle composition was investigated using ICP analysis as well as a Sunset OC/EC analyzer to determine the soot content and the presence of any unburned engine oil. The results show that NOX emissions range between 0.1 g/kWh for a λ of 2.5 and 10 g/kWh λ of 1.5.
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